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High Energy Corporation transition state ts3−2
Transition State Ts3−2, supplied by High Energy Corporation, used in various techniques. Bioz Stars score: 90/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
https://www.bioz.com/product/transition+state+ts3%E2%88%922/transition+state/pm27740760-82-22-21
Average 90 stars, based on 1 article reviews
transition state ts3−2 - by Bioz Stars, 2026-10
90/100 stars

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Article Title: A Radical Mechanism for the Vanadium-Catalyzed Deoxydehydration of Glycols.
Article Snippet: Intermediate 3, still clearly on the singlet surface (the triplet is 52.3 kcal/mol more energetic), proceeds then to 2 through a highenergy transition state ts3−2 (40.4 kcal/mol, corresponding to an activation barrier of 14.2 kcal/mol) that combines a reductive elimination of phosphine oxide with the coordination to vanadium of the previously detached carboxylate ligand.55 Although interesting from a mechanistic point of view, this path is not competitive with the outer-sphere oxygen transfer path that avoids the formation of V(III) complex 2.



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High Energy Corporation transition state ts3−2
Transition State Ts3−2, supplied by High Energy Corporation, used in various techniques. Bioz Stars score: 90/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
https://www.bioz.com/product/transition+state+ts3%E2%88%922/transition+state/pm27740760-82-22-21
Average 90 stars, based on 1 article reviews
transition state ts3−2 - by Bioz Stars, 2026-10
90/100 stars
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